This diagram shows the flat-sheet structure of molybdenum disulfide — molybdenum atoms shown in teal, sulfur atoms in yellow (credit: Han Wang et al.)
MIT researchers — who struggled for several years to build electronic circuits out of graphene with very limited results (except for radio-frequency applications) — have now succeeded in making a variety of electronic components from an amazing new material: a 2D version of molybdenum disulfide (MoS2).
The MIT researchers say the material could help usher in radically new products, from whole walls that glow to clothing with embedded electronics to glasses with built-in display screens.
Tomás Palacios, the Emmanuel E. Landsman Associate Professor of EECS says he thinks graphene and MoS2 are just the beginning of a new realm of research on two-dimensional materials. “It’s the most exciting time for electronics in the last 20 or 30 years,” he says. “It’s opening up the door to a completely new domain of electronic materials and devices.”
A report on the production of complex electronic circuits from the new material was published online this month in the journal Nano Letters, authored by Han Wang and Lili Yu, graduate students in the Department of Electrical Engineering and Computer Science (EECS); Palacios; and others at MIT and elsewhere.
Promises to replace graphene
Like graphene, itself a 2-D form of graphite, molybdenum disulfide has been used for many years as an industrial lubricant. But it had never been seen as a 2-D platform for electronic devices until last year, when scientists at the Swiss university EPFL produced a transistor on the material.
Yi-Hsien Lee, a postdoc in associate professor Jing Kong’s group in EECS, found a good way to make large sheets of the material using a chemical vapor deposition process. Lee came up with this method while working with Lain-Jong Li at Academia Sinica in Taiwan and improved it after coming to MIT. Palacios, Wang and Yu then set to producing building blocks of electronic circuits on the sheets made by Lee, as well as on MoS2 flakes produced by a mechanical method, which were used for the work described in the new paper.
Wang had been struggling to build circuits on graphene for his doctoral thesis research, but found it much easier to do with the new material. There was a “hefty bottleneck” to making progress with graphene, he explains, because that material lacks a bandgap — the key property that makes it possible to create transistors, the basic component of logic and memory circuits. While graphene needs to be modified in exacting ways in order to create a bandgap, MoS2 just naturally comes with one.
The lack of a bandgap, Wang explains, means that with a switch made of graphene, “you can turn it on, but you can’t turn it off. That means you can’t do digital logic.” So people have for years been searching for a material that shares some of graphene’s extraordinary properties, but also has this missing quality — as molybdenum disulfide does.
Because it already is widely produced as a lubricant, and thanks to ongoing work at MIT and other labs on making it into large sheets, scaling up production of the material for practical uses should be much easier than with other new materials, Wang and Palacios say.
Logic elements, memory fabricated
Wang and Palacios were able to fabricate a variety of basic electronic devices on the material: an inverter, which switches an input voltage to its opposite; a NAND gate, a basic logic element that can be combined to carry out almost any kind of logic operation; a memory device, one of the key components of all computational devices; and a more complex circuit called a ring oscillator, made up of 12 interconnected transistors, which can produce a precisely tuned wave output.
Palacios says one potential application of the new material is large-screen displays such as television sets and computer monitors, where a separate transistor controls each pixel of the display. Because the material is just one molecule thick — unlike the highly purified silicon that is used for conventional transistors and must be millions of atoms thick — even a very large display would use only an infinitesimal quantity of the raw materials. This could potentially reduce cost and weight and improve energy efficiency.
Entirely new kinds of devices: entire wall of light, smart windows, eyeglass displays
In the future, it could also enable entirely new kinds of devices. The material could be used, in combination with other 2-D materials, to make light-emitting devices. Instead of producing a point source of light from one bulb, an entire wall could be made to glow, producing softer, less glaring light. Similarly, the antenna and other circuitry of a cellphone might be woven into fabric, providing a much more sensitive antenna that needs less power and could be incorporated into clothing, Palacios says.
The material is so thin that it’s completely transparent, and it can be deposited on virtually any other material. For example, MoS2 could be applied to glass, producing displays built into a pair of eyeglasses or the window of a house or office.
Ali Javey, an associate professor of electrical engineering and computer science at the University of California at Berkeley, who was not involved in this research, says layered materials such as MoS2 are “a promising class of materials for future electronics,” but cautions that while “the future looks bright for layered semiconductors, still work needs to be done to better understand their performance limits and large-scale manufacturing.”
Overall, Javey says, the MIT team’s research is “elegant” work that “takes an important step forward in advancing the field of layered semiconductors.”
Researchers at the U.S. Army Research Laboratory researchers and Academia Sinica in Taiwan were also involved. The work was funded by the U.S. Office of Naval Research, the Microelectronics Advanced Research Corporation Focus Center for Materials, the National Science Foundation and the Army Research Laboratory.